Hi Nogbad, first the mechanics of adding the coloured keyline.
There are several ways but here are two. Firstly you must decide what colour you want by using the picker tool on the photo where you want to sample the colour. This will alter the foreground colour to that selected. Now you can either Select All and Edit>Stroke, decide how many pixels wide you need, select Inside and Foreground Colour then OK. Or you could go to Image>Canvas Size then increase by a given number of pixels or whatever, select foreground colour and OK. The line will be added.
As for the rest you need to Image>Image Size the picture to whatever print size you want, or you could add a white border in Canvas Size to make the whole thing the size you want printing.
Hope some of this makes sense I'm not even sure what prog you use or how much you know your way round it. I'm kinda assuming you are using Photoshop.
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