If your camera can shoot RAW+JPEG, then I'd go for that: you'll have the option of using either. If only RAW or JPEG, then go for RAW if you're happy doing some Photoshop work. You'll have to meter for the bride's dress (assuming white) otherwise there's the danger of blowing any highlights. I've never used flash photography, so couldn't advise on that, but check that it's OK to use (might be distracting for guests). Go for highest ISO that your camera can handle without caausing noise.
There are other members who will be able to give you more and better advise, but hope that this helps.
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