Al,
As you are going to have a go this weekend pick something simple to take a pic of. Start off deciding on the background and the angle you want to take it from and then decide on the position of your main light. Take a few pics to get the best angle from that one flash. Then consider your second unit. Use that to add a highlight or lessen a shadow. The second flash will be on reduced power to not compete with the main/key light.
Don
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